Allyl Caproate (Allyl Hexanoate)
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Aroma Chemicals

Allyl Caproate (Allyl Hexanoate)

Unravel Perfumery ·Aroma Chemicals

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Scent FamilyFruityPineappleSweet

CAS 123-68-2 · Fruity · Pineapple · IFRA specification (allyl esters)

Allyl caproate (allyl hexanoate) is the pineapple ester, the juicy, sweet fruit note behind most pineapple and tropical accords. It is strong and bright, so a small amount goes a long way.

What it smells like

Ripe pineapple with a sweet, fruity-ester brightness and a faint fatty-green edge.

How perfumers use it

Use it to build pineapple, tropical and fruity-cocktail accords, or add a juicy top to florals and fruity chypres. It combines well with other fruity esters and with Aldehyde C-18 for a piña-colada effect. Work from a dilution and keep it in the top of the formula.

Blends well with: Aldehyde C-18, Hedione, Ethyl Maltol, Citrus oils, Musks.

IFRA & regulatory

Covered by IFRA's specification for allyl esters: free allyl alcohol in the material must stay below 0.1%. There is no separate concentration cap on the ester itself.

For use in perfumery, cosmetics and fragrance manufacturing only. Not for ingestion. Handle neat material with gloves and good ventilation. The certificate of analysis (COA) and safety data sheet (SDS) are available on request.

Frequently asked questions

What does allyl caproate smell like?

Sweet, ripe pineapple with a fruity-ester brightness.

Is allyl caproate the same as allyl hexanoate?

Yes. Caproate is the older name for hexanoate; both refer to CAS 123-68-2.

Does IFRA restrict allyl caproate?

Covered by IFRA's specification for allyl esters: free allyl alcohol in the material must stay below 0.1%. There is no separate concentration cap on the ester itself.

Browse more aroma chemicals for perfumery. Technical and regulatory data checked 21 September 2026 against the IFRA Standards (51st Amendment) and the 52nd Amendment consultation outcome.

Pair & layer

Works beautifully with

Starting points built from our own catalogue. Dosages are % of the finished oil or parts by weight; adjust by smell.

Accord

Green pineapple fresh top

Sparkling green-fruity freshness for aquatic and sporty scents.

Use at 5–15% of a fresh formula.

Suggested levels are kept within IFRA fine-fragrance limits for the added material. Your oil already contains other materials, so check the finished blend against the IFRA Standards before selling.

Official documents and compliance certificates for this product. Always verify IFRA usage levels from the official compliance sheets before formulation.

IFRA Compliance SheetPDF
Safety Data Sheet (SDS)PDF

Documents will appear here once uploaded via the custom.certifications metafield.Request via WhatsApp →

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Technical profile

Allyl Caproate (Allyl Hexanoate), at a glance

Technical & regulatory data checked 21 Sep 2026

Molecule
C9H16O2
Chemical name
Prop-2-enyl hexanoate (allyl hexanoate)
CAS number
123-68-2
Molecular weight
156.22 g/mol
Appearance
Colourless liquid
Solubility
soluble in ethanol (1:2 in 80%), fixed oils, paraffin oil; insoluble in PG
Flash point
66 °C
Also known asAllyl hexanoateAllyl caproate
Performance
Note positionTop
Odour strengthHigh
Tenacity on strip~1 h
Fleeting2 weeks+
Typical useUp to 6% of the concentrate
Odour profile
Fruity · Pineapple
Pineapplesweetfruityslightly fatty-green
Regulatory
IFRA specification (allyl esters)

Limits for other product types differ. Always check the current IFRA Standards and your local cosmetic regulations before finalising a formula.

Handling & dilution

Strong and diffusive; a 10% dilution makes dosing easier.

Formulating with this material?

Start with a small pack, move to bulk when your formula is locked. Documents and bulk pricing are one message away.